| Name | Address | Enrollment | Grade span |
|---|---|---|---|
| Big Ridge Elementary School | 3420 Hickory Val Road | 229 | K-5 |
| H Maynard Middle School | 435 Main Street | 692 | 6-8 |
| Maynardville Elementary School | 615 Main Street | 667 | K-5 |
| Union County Alternative Center School | 115 Wilson Lane | 24 | 6-12 |
| Union County High School | P. O. Box 249 | 980 | 9-12 |
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